56 A method to form carbon-nitrogen bonds via nitro group reduction could streamline synthetic routes in medicinal chemistry.
http://www.sciencemag.org/content/348/6237/886.abstract
55 Self-assembly of dynamic orthoester cryptates.
http://www.nature.com/ncomms/2015/150522/ncomms8129/full/ncomms8129.html
54 Total synthesis of (+)-gelsemine via an organocatalytic Diels–Alder approach.
http://www.nature.com/ncomms/2015/150521/ncomms8204/full/ncomms8204.html
53 Synthesis of many different types of organic small molecules using one automated process.
http://www.sciencemag.org/content/347/6227/1221
52 Carbon–carbon bond activation of cyclobutenones enabled by the addition of chiral organocatalyst to ketone.
http://www.nature.com/ncomms/2015/150205/ncomms7207/full/ncomms7207.html
51 Metal-catalysed azidation of tertiary C–H bonds suitable for late-stage functionalization.
http://www.nature.com/nature/journal/v517/n7536/full/nature14127.html
50 A catalyst to selectively reverse a common chemical reaction offers versatile opportunities in molecular synthesis.
http://www.sciencemag.org/content/347/6217/56.abstract
49 One-pot room-temperature conversion of cyclohexane to adipic acid by ozone and UV light.
http://www.sciencemag.org/content/346/6216/1495.abstract
48 Crystalline-gradient polycarbonates prepared from enantioselective terpolymerization of meso-epoxides with CO2.
http://www.nature.com/ncomms/2014/141205/ncomms6687/full/ncomms6687.html
47 Iron catalysed direct alkylation of amines with alcohols.
http://www.nature.com/ncomms/2014/141126/ncomms6602/full/ncomms6602.html
46 Formic-acid-induced depolymerization of oxidized lignin to aromatics.
http://www.nature.com/nature/journal/v515/n7526/full/nature13867.html
45 A network of sodium and magnesium ions helps direct double deprotonation of aryl rings.
http://www.sciencemag.org/content/346/6211/834.abstract
44 Graphenes in the absence of metals as carbocatalysts for selective acetylene hydrogenation and alkene hydrogenation.
http://www.nature.com/ncomms/2014/141024/ncomms6291/full/ncomms6291.html
43 Assembly-line synthesis of organic molecules with tailored shapes.
http://www.nature.com/nature/journal/v513/n7517/full/nature13711.html
42 Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2.
http://www.sciencemag.org/content/345/6196/546.abstract
41 Combining two catalysts, one light-activated, facilitates bond formation between saturated and unsaturated carbons.
http://www.sciencemag.org/content/345/6195/433.abstract
40 An iodide salt with a chiral counterion proves an efficient catalyst for preparation of compounds analogous to vitamin E.
http://www.sciencemag.org/content/345/6194/291.abstract
39 Natural products citrinalin B and cyclopiamine B, which contain basic nitrogen atoms that are susceptible to oxidation during synthesis, can be synthesized by the selective introduction and removal of functional groups.
http://www.nature.com/nature/journal/v509/n7500/full/nature13273.html
38 A two-catalyst combination offers long-sought selectivity in intermolecular coupling of olefins to form four-membered rings.
http://www.sciencemag.org/content/344/6182/392.abstract
37 A catalyst that adds silyl groups to specific sites on aryl rings could streamline synthesis of pharmaceutical intermediates.
http://www.sciencemag.org/content/343/6173/853.abstract
36 Direct Stereospecific Synthesis of Unprotected N-H and N-Me Aziridines from Olefins.
https://www.sciencemag.org/content/343/6166/61.abstract
35 Organic chemistry of balms used in the preparation of pharaonic meat mummies.
http://www.pnas.org/content/110/51/20392.abstract
34 Supramolecular high-aspect ratio assemblies with strong antifungal activity.
http://www.nature.com/ncomms/2013/131209/ncomms3861/full/ncomms3861.html
33 Nanoscale Fe2O3-Based Catalysts for Selective Hydrogenation of Nitroarenes to Anilines.
http://www.sciencemag.org/content/342/6162/1073.abstract
32 A mild fluorination method could help produce compounds of interest in medicinal research.
http://www.sciencemag.org/content/342/6161/956.abstract
31 Chemical synthesis of lactic acid from cellulose catalysed by lead(II) ions in water.
http://www.nature.com/ncomms/2013/130711/ncomms3141/full/ncomms3141.html
30 Metal-free oxidation of aromatic carbon–hydrogen bonds through a reverse-rebound mechanism.
http://www.nature.com/nature/journal/v499/n7457/full/nature12284.html
29 Two catalysts independently set the chiral sense of adjacent stereocenters in a carbon–carbon bond-forming reaction.
http://www.sciencemag.org/content/340/6136/1065.abstract
28 An iron catalyst facilitates carbon–nitrogen bond formation in previously unreactive substrates.
http://www.sciencemag.org/content/340/6132/591.abstract
27 Construction of Robust Enzyme Nanocapsules for Effective Organophosphate Decontamination, Detoxification, and Protection.
http://onlinelibrary.wiley.com/doi/10.1002/adma.201205138/abstract
|
