152 Solar-driven efficient and selective ammonia recovery from ammonium-containing wastewater
https://www.nature.com/articles/s41893-025-01609-6
151 Sustainable synthesis of polymer-grade ethylene via electrified acetylene semihydrogenation
https://www.pnas.org/doi/10.1073/pnas.2505151122
150 Catalytic allylation of native hexoses and pentoses in water with indium
https://www.nature.com/articles/s41586-025-08690-z
149 Methane oxidation to ethanol by a molecular junction photocatalyst
https://www.nature.com/articles/s41586-025-08630-x
148 Synthesis of ethane from CO2 by a methyl transferase–inspired molecular catalyst
https://www.pnas.org/doi/10.1073/pnas.2417764122
147 Photocatalytic furan-to-pyrrole conversion
https://www.science.org/doi/10.1126/science.adq6245
146 Spin-mediated promotion of Co catalysts for ammonia synthesis
https://www.science.org/doi/10.1126/science.adn0558
145 Continuous ammonia synthesis from water and nitrogen via contact electrification
https://www.pnas.org/doi/10.1073/pnas.2318408121
144 A light-driven enzymatic enantioselective radical acylation
https://www.nature.com/articles/s41586-023-06822-x
143 A simple cobalt catalyst active for hydroformylation can also couple alkenes, amines, and carbon monoxide under photochemical conditions.
https://www.science.org/doi/10.1126/science.adk2312
142 Formaldehyde regulates S-adenosylmethionine biosynthesis and one-carbon metabolism
https://www.science.org/doi/full/10.1126/science.abp9201
141 Preparation of methanediamine (CH2(NH2)2)—A precursor to nucleobases in the interstellar medium.
https://www.pnas.org/doi/10.1073/pnas.2217329119
140 Nickel-catalyzed hydrogenative coupling of nitriles and amines for general amine synthesis.
https://www.science.org/doi/10.1126/science.abn7565
139 Making hydrogen peroxide in situ could improve overall process efficiency for production of a key nylon precursor.
https://www.science.org/doi/10.1126/science.abl4822
138 The state of zinc in methanol synthesis over a Zn/ZnO/Cu(211) model catalyst.
https://www.science.org/doi/10.1126/science.abj7747
137 Catalytic synthesis of phenols with nitrous oxide.
https://www.nature.com/articles/s41586-022-04516-4
136 Synthesis of a natural product and derivatives by a late-stage oxidative dimerization sheds light on its antibiotic activity.
https://www.science.org/doi/10.1126/science.abm6509
135 Modular terpene synthesis enabled by mild electrochemical couplings.
https://www.science.org/doi/10.1126/science.abn1395
134 Carbon nanotube supported oriented metal organic framework membrane for effective ethylene/ethane separation.
https://www.science.org/doi/10.1126/sciadv.abm6741
133 Synthesis of methanediol [CH2(OH)2]: The simplest geminal diol.
https://www.pnas.org/content/119/1/e2111938119
132 A solution of ethylene diamine and lithium in tetrahydrofuran rapidly and selectively reduces aromatics.
https://www.science.org/doi/10.1126/science.abk3099
131 Cleaving arene rings for acyclic alkenylnitrile synthesis.
https://www.nature.com/articles/s41586-021-03801-y
130 Diamines are formed at benzylic and adjacent alkyl carbons using acetonitrile as the nitrogen source.
https://science.sciencemag.org/content/371/6529/620
129 A software platform translates the organic chemistry literature into a format executable by automated laboratory apparatus.
https://science.sciencemag.org/content/370/6512/101
128 A photochemical dehydrogenative strategy for aniline synthesis.
https://www.nature.com/articles/s41586-020-2539-7
127 Common organic reactions mechanically perturb solvents and increase molecular mobility beyond simple Brownian diffusion.
https://science.sciencemag.org/content/369/6503/537
126 Ammonia is synthesized using a dual-site approach, whereby nitrogen vacancies on LaN activate N2, which then reacts with hydrogen atoms produced over the Ni metal to give ammonia.
https://www.nature.com/articles/s41586-020-2464-9
125 Rationally designed indium oxide catalysts for CO2 hydrogenation to methanol with high activity and selectivity.
https://advances.sciencemag.org/content/6/25/eaaz2060
124 A methylphenanthroline iridium catalyst rapidly adds boron to primary C–H bonds and beta C–H bonds in saturated heterocycles.
https://science.sciencemag.org/content/368/6492/736
123 A one-step, three-component radical coupling of [1.1.1]propellane by a photoredox reaction mediated by a copper catalyst produces drug-like bicyclopentanes.
https://www.nature.com/articles/s41586-020-2060-z
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